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In the latter years of your life, your happiness and your self-esteem will be determined by the mountains you surmounted, the valleys you climbed out of, and the life and/or career that you forged for yourself.īut ain’t I lucky I can still breathe in. People will try to peck you to death like a duck but you’re not in it.’ This is my advice to all of you when others dare to disgrace your name. Once when Oprah Winfrey was upset by a story in a tabloid I encouraged her to understand, ‘You’re not in it. For it is your job to pay for those who are yet to come. So, when you enter a challenging situation, bring them on the stage with you let their distant voices add timbre and strength to your words. But for the sacrifices made by some of your ancestors, you would not be here they have paid for you. Each of you, Black, White, Brown, Yellow, Red-whatever pigment you use to describe yourselves-has been paid for. Stand up straight and realize who you are, that you tower over your circumstances. There is no failure as long as you learn from your experience, continue to work, and continue to press on for success. And that I have the responsibility to give the best treatment I can to other people. Dignity really means that I deserve the best treatment I can receive. Dignity means that what I have to say is important, and I will say it when it’s important for me to say it. Over time I have learned I am at my best around books. Her writing touched on themes of struggle and sadness, and often drew on her faith as a source of strength to find beauty and perseverance in hard times. It means a belief in oneself, that one is worthy of the best. For a person who grew up in the 30s and 40s in the segregated South, with so many doors closed without explanation to me, libraries and books said, Here I am, read me. Maya Angelou spent her life as an unstoppable force for art, justice, and love. And let faith be the bridge you build to overcome evil and welcome good.ĭignity doesn’t just mean always being stiff and composed. It jumps hurdles, leaps fences, penetrates walls to arrive at its destination full of hope. The world gives you way more than you ever give it. When we find someone who is brave, fun, intelligent, and loving, we have to thank the universe. Let gratitude be the pillow upon which you kneel to say your nightly prayer. Give thanks for a little and you will find a lot. Let gratitude be the pillow upon which you kneel to say your nightly prayer. In all affairs, it’s a healthy thing now and then to hang a question mark on the things you have long taken for granted. Here’s a look into my trip planning process – I hope it gives you a few ideas! I also used these spreadsheets for a quick 10 day road trip around New Zealand and they worked great – simple, quick and easy – I wish I thought to use Excel for trip planning sooner! The spreadsheets can be used for any / every domestic and international trip. I started out with a budget spreadsheet and ended up with a few spreadsheets to organize everything: I’ve used various methods for travel planning in the past including a printable planner, bullet journal and attempted to (but quickly abandoned) various travel apps.įor this trip I wanted something I could use to keep everything in the one place. I’m off to Europe later this year! This is the biggest trip I’ve done to date – almost 7 weeks. I’ve purchased printables from you – how should I set up my planner?.What is a Printable? What happens when I purchase a printable from you?.Why printables? Do you sell printed versions of your products?.Shop my favorite planner supplies on Amazon.200 Blog Post Title Prompts (For Any Type of Blog).54 Mistakes Etsy Sellers Make (And How to Fix Them).
This is not the place for requesting invitations to music trackers. It will not be tolerated.ĭo not request or offer invites to trackers or other private music sharing sites. Do not harass other members of this community for their music or access to their files, or request access to files in a way that comes across as entitled. Users frequently choose to generously share music through various outlets. Read the Rulesĭo not beg for access to music or make demands regarding requests. Make sure to check out the wiki for more info. Whatever your persuasion, if you hold an interest in anything relating to the above-then you'll fit right in! Others just wish to learn about music formatting, organizing and pirating. Some collect purely for rare and obscure music, to preserve pieces which might otherwise be lost in time. Some hoard music because they believe that the internet will not remain free and open in the foreseeable future. We are a group of people engaged in collecting as much digital music as possible. Other operating systems: The latest MediaHuman Audio Converter version from 2024 is also available for Mac.Home of the compulsive music collectors who are looking to expand, archive or organize their music library. It comes in both 32-bit and 64-bit downloads. Previous versions of the OS shouldn't be a problem with Windows 8 and Windows 7 having been tested. MediaHuman Audio Converter can be used on a computer running Windows 11 or Windows 10. What version of Windows can MediaHuman Audio Converter run on? 2.2.2 is the latest version last time we checked. Download and installation of this software is free, however other similar programs are available from media converter software which may have what you need. MediaHuman Audio Converter is a restricted version of commercial software, often called freemium which requires you to pay a license fee to unlock additional features which are not accessible with the free version.
Simply download our handy Ring Size Guide and print at home. There are also a number of at-home methods to find your ring size. If you do not see the size you need, contact our experts for help placing a special order. These standard ring sizes can help guide you in the right direction. With the above tips in mind, it's now time to get measuring. The most commonly purchased men's rings range between size 8 to 10. This will help ensure that your size is more accurate. For the best results, it's a good idea to measure your chosen finger 3 or 4 times at various points in the day and take the average measurement as your true size. When it comes to measuring the chosen finger, ensure you are measuring using the hand you intend to wear the ring on.ģ. Also worth remembering is that your dominant hand and fingers will likely be slightly larger than your other hand. Try and do any home measuring when you're relaxed and your fingers are neither too warm nor too cold.Ģ. If you're warm, your fingers will likely be larger than they might be on a cold day. Your fingers can change size over the course of the day. Before we get into those, however, there are some things you might need to consider before measuring your ring finger at home.ġ. Our downloadable size chart contains two of the most highly accurate home measurement methods. In the past, methods have included using a piece of string to measure your or your partner's finger all the way through to guessing the size from eye. Measuring your ring size at home can be a great way to find the perfect size, giving you all the confidence you need before you head into store or purchase your dream ring online. Furthermore, the corrected partition function also overcomes technical difficulties and leads to an increased stability of the calculations in regard to the size of the cluster set. Standand Enthalpies of Formation & Standard Entropies of Common Compounds. The reason is that the entropies listed are absolute, rather than relative to some arbitrary standard like enthalpy. Since we now know the entropy at T 0 K and we can calculate the entropy change for a temperature and phase change, we can then calculate the absolute entropy. The effect of the corrected partition function is visible in the different populations of clusters, which become physically more meaningful in that larger clusters are higher populated in the liquid phase and the gas phase is mainly populated by the monomers. By convention, fH (T) f H ( T) for the elements in their most stable modifications is zero. It is also possible, using more advanced theoretical thermodynamics, to determine S experimentally by measuring heat capacities and enthalpies of phase transitions. By definition, the standard enthalpy of formation (at a certain temperature) of a complex substance AB is equal to the enthalpy of a chemical process A + B AB, where A and B are elements in their most stable modifications (at a certain temperature). Now there you have them, the textbook entropies of ions, which are not quite absolute. It is kind of natural to consider its entropy 0 0, much like the absolute elevation of the sea level is 0 0. Sci., 2021, 12, 6551 DOI: 10.1039/D1SC00621E This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. It is possible, though exceedingly difficult, to calculate the entropy of any system under any conditions of interest from the equation SklnW. Why, lets say it is HX+ H X +, because so much of our chemistry is dominated by the acid/base equilibria. The enthalpies and entropies of vaporization show improvements from 6.5 error to 3.3 kJ mol −1 deviation to experiment and from 28.4 error to 13.5 J mol −1 K −1 deviation to experiment, respectively. Calculation of absolute molecular entropies and heat capacities made simple P. The new scheme is tested on a set of nine organic solvents for the calculation of the enthalpy and entropy of vaporization. Here, the low energy vibrational frequencies in the vibrational partition function are treated as hindered rotations instead of vibrations. The second, based on the fact that entropy is a state function, uses a thermodynamic. The first, based on the definition of absolute entropy provided by the third law of thermodynamics, uses tabulated values of absolute entropies of substances. The changes are based on a previously suggested modification of the molecular entropy calculation in the gas phase. In this section, we examine two different ways to calculate S for a reaction or a physical change. In this work, we present an altered partition function that leads to an improved calculation of the enthalpy and entropy of vaporization in the framework of quantum cluster equilibrium theory. Thursday’s report, at first glance, appears to be yet another example of the long and bumpy process to bring down inflation. What this means for the Fed’s rate cut plans “It’s mostly, ‘steady as she goes,’” she added. “It wasn’t surprisingly good news, which would always be welcome, but nothing too concerning.” “I don’t think that there’s anything wildly concerning in this report,” Wendy Edelberg, director of The Hamilton Project and senior fellow in economic studies at Brookings, told CNN. On a monthly basis, core CPI rose 0.3%, in line with expectations. When removing the more volatile categories of food (which increased 0.2% on the month) and energy (which ticked up 0.4%), core CPI measured 3.9% annually, a step back from November’s 4% reading and the lowest annual increase that index has seen since May 2021. In December, gas prices stayed mostly in neutral, rising 0.2%, while rising shelter costs accounted for more than half of the monthly all-items increase, according to the BLS report.Įconomists were expecting the annual overall inflation rate to tick higher, to 3.2% from the 3.1% headline reading the month before, according to FactSet consensus estimates.ĭespite the acceleration, the annual rate of consumer-level inflation is down considerably from December 2022’s rate of 6.5% additionally, a closely watched measure of underlying inflation slowed further. The monthly and annual numbers for December were higher than those seen in November, when tumbling gas prices drove the overall index lower. The Consumer Price Index, which measures the average price changes for commonly purchased goods and services, rose 0.3% in December from the month before, matching expectations, according to Bureau of Labor Statistics data released Thursday. US consumer prices rose 3.4% annually to close out 2023, capping a year of substantial progress on efforts to rein in painfully high inflation. In Villain-Con, Bob meets Professor Flux, who invented a time machine, but the professor is killed by one of his future avatars. He is quite excited when he sees some information from VNC, a top secret channel about villains. Kevin hands him his teddy bear just before the light goes out. Kevin goes into the room, and Bob tells Kevin he misses the tribe. In the room, he sees lots of mirrors on the wall seeing his reflection, he thinks it is his buddies, he runs bumping into it and discovers it's not real. Kevin grabs the loudspeaker of the store and calls Bob, while Bob enters a changing room, thinking Kevin is inside. Then, he enters a department store while Kevin and Stuart search for him after noticing him missing. Soon, Bob is accidentally brought into the taxi with the woman's baggage by the taxi driver she soon, notices Bob and shrieks then throws him and his teddy bear out. Later, the trio visit an album store, and Bob follows a female customer because her clothes have lots of bananas drawn on it. When arriving to New York, Bob is quite interested in a parade against the war, so he holds a sign with "BOO-YA!" on it. Bob is tired, grew hungry halfway through the journey and tries to eat Kevin with Stuart, who has a hallucination that the minions are speaking bananas. On the way to their destination, Kevin carried him sometimes. His green eye is slightly lighter.īob was the only Minion interested in Kevin's journey, after begging him he was able to join. He looks similar to Jerry except without hair. He also tries to attack a butterfly, but fails & accidentally falls off into the void. He is playful and brings much annoyance to Kevin. īob first appears during the credits of Despicable Me 2, where is auditioning for the spin-off film Minions along with Kevin and Stuart. Is also shown more mature, albeit still playful, as well as more of a goofball like all the other Minions.īob with Kevin and Stuart in the audition of the spin-off film Minions. However, in the audition scene in Despicable Me 2 (having grown since the time of Minions), he became more plumper which made him look more like the short and plump Minions with spiky hair, just no hair. He also enjoys bedtime stories and playing with his favorite stuffed teddy bear, Tim. He is described as a "Little Brother" who finds love in anything and everything, including a rat (who he named Poochy) he found in a sewer in the Minions film. He often carries around a teddy bear that he owns called Tim, which is brown with yellow buttoned eyes.īob is a Minion who is more childish and immature than most of the other Minions. This mini-movie marks the return of both Vector and Bob.Bob is a short and bald Minion with heterochromia.The first was Mower Minions followed by Yellow is the New Black.This is the third mini-movie to be released along with a feature film.Pierre Coffin as Tim, Larry, Jorge and Bob.Disappointed, Vector says again "Oh, poop," just like he did in the beginning. They fly off, leaving the unlucky Vector behind. The alien becomes friends with the minions (who were also unharmed from the crash, due to being indestructible) and decides to give them a ride back to Earth. Suddenly, a green Martian appears and says something to Vector, but he couldn’t understand what he was saying. Vector wakes up, recovering from the collision, only to realize that he is not on Earth, but Mars. Vector chases the minions with his rocket satellite and they cause a huge collision. The four then try to call Vector, but he ignores them. At that moment, Jorge, Tim and Larry come with Gru's airship to pick up Bob. He then sees Bob (the floating minion), who makes them go back to the moon sole.Īfter many attempts, like a floating balloon suit, and a slingshot, Vector comes up with an idea to which he will use his backside rockets to the space satellite. While on the moon (following his defeat), Vector starts to panic, but soon realizes that he can get out of there by jumping high. The short begins with a recap of the events of the first film, with the MSNBC's anchorman telling about Vector being lifted to space by the Moon and a minion who drank the anti-gravity serum. The short is set after the events of the first film. Mooned is a short film that is attached to Migration and features Minions and Vector as they attempt to leave the moon. (conda-snap) VA030LWJHD2:snappy hao_yan$ /Users/hao_yan/opt/anaconda3/envs/conda-snap/bin/python setup.py install Users/hao_yan/opt/anaconda3/envs/conda-snap/bin/python setup.py install snappy-conf, and there was no error (just hanging Configuring SNAP-Python interface…), I went ahead and run the following:
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